【公開日:2023.07.31】【最終更新日:2023.05.16】
課題データ / Project Data
課題番号 / Project Issue Number
22UT0047
利用課題名 / Title
環状超分子口縁部におけるイオン結合による新規分子認識機能の開拓
利用した実施機関 / Support Institute
東京大学 / Tokyo Univ.
機関外・機関内の利用 / External or Internal Use
内部利用(ARIM事業参画者以外)/Internal Use (by non ARIM members)
技術領域 / Technology Area
【横断技術領域 / Cross-Technology Area】(主 / Main)計測・分析/Advanced Characterization(副 / Sub)-
【重要技術領域 / Important Technology Area】(主 / Main)次世代ナノスケールマテリアル/Next-generation nanoscale materials(副 / Sub)-
キーワード / Keywords
X線回折/X-ray diffraction,質量分析/Mass spectrometry,赤外・可視・紫外分光/Infrared and UV and visible light spectroscopy,電子顕微鏡/Electron microscopy,X線回折/X-ray diffraction,電子回折/Electron diffraction,ナノカーボン/ Nano carbon
利用者と利用形態 / User and Support Type
利用者名(課題申請者)/ User Name (Project Applicant)
緒方 嵩隼
所属名 / Affiliation
東京大学
共同利用者氏名 / Names of Collaborators in Other Institutes Than Hub and Spoke Institutes
ARIM実施機関支援担当者 / Names of Collaborators in The Hub and Spoke Institutes
利用形態 / Support Type
(主 / Main)機器利用/Equipment Utilization(副 / Sub)-
利用した主な設備 / Equipment Used in This Project
報告書データ / Report
概要(目的・用途・実施内容)/ Abstract (Aim, Use Applications and Contents)
The crystal structure of the cyclodextrin metal-organic framework (CD-MOF) was analyzed by utilizing VariMax Dual single crystal X-ray apparatus. Structures of two CD-MOFs consisting of different metal cations, CDMOF-K and CDMOF-Cs, were successfully determined.
実験 / Experimental
The single-crystal structure analysis of CDMOF-K and CDMOF-Cs were performed using VariMax Dual apparatus.
結果と考察 / Results and Discussion
The obtained crystal structures of CDMOFs provided new insights into the structural properties of these MOFs, especially about their nanoporous nature. CDMOF-K formed nano-sized spherical pore with the radius of around 1.2 nm and CDMOF-Cs formed one-dimensional linear pore with diameter of around 0.6 nm. These insights are expected to provide important hints toward effective molecular recognition using CD-MOFs.
図・表・数式 / Figures, Tables and Equations
その他・特記事項(参考文献・謝辞等) / Remarks(References and Acknowledgements)
成果発表・成果利用 / Publication and Patents
論文・プロシーディング(DOIのあるもの) / DOI (Publication and Proceedings)
口頭発表、ポスター発表および、その他の論文 / Oral Presentations etc.
特許 / Patents
特許出願件数 / Number of Patent Applications:0件
特許登録件数 / Number of Registered Patents:0件